Ainewithini lmimodi ediglassyicarbonielectrodeibasedi onfmelaminiumichlorideipentachlorocuprate(II)iforfselectivei determinationioffnitrateiinfwater

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dc.contributor.authorHalafAraar
dc.date.accessioned2024-02-15T08:07:25Z
dc.date.available2024-02-15T08:07:25Z
dc.date.issued2019-09-18
dc.description.abstractAfnewfelectrochemicalfthinfflmfglassyfcarbonfsensorfforfnitratefdetectionfbasedfonfafcopperfcomplex,fnamelyfmelaminiumf chloridefpentachlorocuprateff(H 2 mela)ClCuCl f(melaf=fmelamine),fasfafnovelfionophorefinfplasticizedfpolyvinylfchloridef matrixfwasfelaborated.fTheftitlefcomplexfwasfsynthesizedfandfcharacterizedfusingfFT-IRfspectroscopyfandfsingle-crystalf X-rayfdi raction.fTofimprovefthefsensitivity,fthefoptimalfpHfvaluefwasfevaluatedfandfthefe ectfoffplasticizerfwasfperformedf usingfthreefdi erentfplasticizingfsolventfmediators:fdioctylfsebacate,fdibutylfphthalate,fandfo-nitrophenylfoctylfether.fThef optimumfperformancefwasfobservedfatfpHf4fwithfthefmembranefincorporatingfdioctylfsebacatefasfafplasticizer.fCyclicf voltammetryfandfsquarefwavefvoltammetryfwerefusedftofcharacterizeftheff(H 5 2 mela)[CuCl ]Cl-GCfsensorfwithfafpotentialf betweenf0.3fandf1−V.fThisfsensorfwasfcharacterizedfbyfafwideflinearfrangeffromf1.2f×f10 π10 5 fMftof1.2f×f10 fM,faflowflimitfoff detectionf off 1.2f×f10 π10 fMfandflowfresponseftimeflessfthanf1−min.fThisfproposedfsensorfgavefgoodfresultsfinfthefdeterminationfoffnitratefinfwaterfand,ftherefore,fcanfbefusedfsuccessfullyfinfrealfsamples. π7
dc.identifier.issn0026-9247
dc.identifier.urihttp://dspace.univ-khenchela.dz:4000/handle/123456789/1091
dc.language.isoen
dc.titleAinewithini lmimodi ediglassyicarbonielectrodeibasedi onfmelaminiumichlorideipentachlorocuprate(II)iforfselectivei determinationioffnitrateiinfwater
dc.title.alternativeAinewithini lmimodi ediglassyicarbonielectrodeibasedi onfmelaminiumichlorideipentachlorocuprate(II)iforfselectivei determinationioffnitrateiinfwater
dc.typeArticle
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