Synthesis, Characterization and properties studies of new magnetic materials
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Date
2015
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Abstract
We are interested in molecular polymetallic species having high spin and
nuclearities in relation to the field of so call single-molecule magnets (SMMs). The goal is to
find a way to synthesis metal clusters which may have application in magnetism and nanosciences. With this purpose, we decided to investigate the coordination chemistry of the Schiff
base.Along this way we were able to create cubane-like complexes and elaborate new Single
Molecule-Magnets. The idea was to use Schiff base ligands and different metals to generate
high nuclear complexes. Complexation of Shiff base with copper has been investigated.
Tetranuclear complex with a cubane like core have been synthesised with (Sciff base), with the
same base and cobalt we obtains an other single magnetic complex completely different.