Diaquabis(ethylenediamine-j2N,N00)- copper(II) bis(sulfamerazinate)

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2014-05-09
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The asymmetric unit of the title compound, [Cu(C2H8N2)2- (H2O)2](C11H11N4O2S)2, contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The CuII cation shows a strong Jahn–Teller distortion. It is coordinated by four N atoms of two ethylenediamine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N—H N, O—H N, N—H O and O—H O hydrogen bonding into a two-dimensional network parallel to (001).
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